Werndl, Charlotte and Frigg, Roman (2014) Rethinking Boltzmannian Equilibrium. In: UNSPECIFIED.
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Abstract
Boltzmannian statistical mechanics partitions the phase space into macro- regions, and the largest of these is identified with equilibrium.
What justifies this identification? Common answers focus on Boltzmann's combinatorial argument, the Maxwell-Boltzmann
distribution, and maximum entropy considerations. We argue that they fail and present a new answer. We characterise
equilibrium as the macrostate in which the system spends most of its time and prove a new theorem establishing that equilibrium thus defined corresponds to the largest macroregion. Our derivation is completely general in that it does not rely on assumptions about the system's dynamics or internal interactions.
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Item Type: | Conference or Workshop Item (UNSPECIFIED) | |||||||||
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Additional Information: | Forthcoming in: Philosophy of Science | |||||||||
Keywords: | statistical mechanics, Boltzmann, equilibrium, approach to equilibrium, thermodynamic-like behaviour | |||||||||
Subjects: | Specific Sciences > Complex Systems Specific Sciences > Physics > Classical Physics Specific Sciences > Physics Specific Sciences > Physics > Statistical Mechanics/Thermodynamics |
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Depositing User: | Charlotte Werndl | |||||||||
Date Deposited: | 18 Jun 2014 14:39 | |||||||||
Last Modified: | 18 Jun 2014 14:39 | |||||||||
Item ID: | 10756 | |||||||||
Subjects: | Specific Sciences > Complex Systems Specific Sciences > Physics > Classical Physics Specific Sciences > Physics Specific Sciences > Physics > Statistical Mechanics/Thermodynamics |
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Date: | 2014 | |||||||||
URI: | https://philsci-archive.pitt.edu/id/eprint/10756 |
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